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Set-on-Demand Geopolymer Using Print-Head Mixing for 3D Concrete Printing (2022-02)

10.1016/j.cemconcomp.2022.104451

 Muthukrishnan Shravan,  Ramakrishnan Sayanthan,  Sanjayan Jay
Journal Article - Cement and Concrete Composites, Vol. 128

Abstract

The concept of set-on-demand in concrete with an intervention at the print head could be used to accelerate the concrete's yield strength development after placement without significantly affecting the pumpability and extrudability. This study demonstrates the proof-of-concept of the set-on-demand approach in geopolymer concrete, where the initial mixing of reactive components (i.e., activators + binder) is conducted at the print head. The study first analyses the feasibility of the proposed concept by assessing the yield strength development rates of fresh concrete for varying mix design parameters. With a suitable mix design is chosen, a modular in-line dynamic mixing equipment was utilised to assess the effect of various mixing regimes and operating parameters (shearing histories) on the yield strength development rates. The results demonstrated that the in-line mixing process of reactive components for a short duration (i.e. 45 secs) would be sufficient to achieve a yield strength development rate of 800 Pa/s after placement, making it suitable for the print-head mixing process. The rapid setting of geopolymer concrete was utilised to print out-of-plane structures (simply supported beams) as a proof of concept.

17 References

  1. Arunothayan Arun, Nematollahi Behzad, Ranade Ravi, Khayat Kamal et al. (2021-10)
    Digital Fabrication of Eco-Friendly Ultra-High-Performance Fiber-Reinforced Concrete
  2. Bentz Dale, Jones Scott, Bentz Isaiah, Peltz Max (2019-02)
    Towards the Formulation of Robust and Sustainable Cementitious Binders for 3D Additive Construction by Extrusion
  3. Burger Joris, Lloret-Fritschi Ena, Scotto Fabio, Demoulin Thibault et al. (2020-04)
    Eggshell:
    Ultra-Thin Three-Dimensional Printed Formwork for Concrete Structures
  4. Mai (née Dressler) Inka, Freund Niklas, Lowke Dirk (2020-01)
    The Effect of Accelerator Dosage on Fresh Concrete Properties and on Inter-Layer Strength in Shotcrete 3D Printing
  5. Markin Slava, Šahmenko Genādijs, Nerella Venkatesh, Näther Mathias et al. (2019-11)
    Investigations on the Foam-Concrete Production Techniques Suitable for 3D Printing with Foam-Concrete
  6. Mohan Manu, Rahul Attupurathu, Schutter Geert, Tittelboom Kim (2021-01)
    Early-Age Hydration, Rheology and Pumping Characteristics of CSA Cement-Based 3D Printable Concrete
  7. Mohan Manu, Rahul Attupurathu, Tittelboom Kim, Schutter Geert (2020-10)
    Rheological and Pumping Behavior of 3D Printable Cementitious Materials with Varying Aggregate Content
  8. Muthukrishnan Shravan, Kua Harn, Yu Ling, Chung Jacky (2020-05)
    Fresh Properties of Cementitious Materials Containing Rice-Husk-Ash for Construction 3D Printing
  9. Muthukrishnan Shravan, Ramakrishnan Sayanthan, Sanjayan Jay (2020-07)
    Buildability of Geopolymer Concrete for 3D Printing with Microwave-Heating
  10. Muthukrishnan Shravan, Ramakrishnan Sayanthan, Sanjayan Jay (2020-09)
    Effect of Microwave-Heating on Inter-Layer Bonding and Buildability of Geopolymer 3D Concrete Printing
  11. Muthukrishnan Shravan, Ramakrishnan Sayanthan, Sanjayan Jay (2021-06)
    Technologies for Improving Buildability in 3D Concrete Printing
  12. Panda Biranchi, Bhagath Singh Gangapatnam, Unluer Cise, Tan Ming (2019-02)
    Synthesis and Characterization of One-Part Geopolymers for Extrusion-Based 3D Concrete Printing
  13. Panda Biranchi, Ruan Shaoqin, Unluer Cise, Tan Ming (2018-11)
    Improving the 3D Printability of High-Volume Fly-Ash Mixtures via the Use of Nano-Attapulgite-Clay
  14. Panda Biranchi, Tan Ming (2018-03)
    Experimental Study on Mix Proportion and Fresh Properties of Fly-Ash-Based Geopolymer for 3D Concrete Printing
  15. Reiter Lex, Wangler Timothy, Anton Ana-Maria, Flatt Robert (2020-05)
    Setting-on-Demand for Digital Concrete:
    Principles, Measurements, Chemistry, Validation
  16. Reiter Lex, Wangler Timothy, Roussel Nicolas, Flatt Robert (2018-06)
    The Role of Early-Age Structural Build-Up in Digital Fabrication with Concrete
  17. Zhang Nan, Xia Ming, Sanjayan Jay (2021-10)
    Short-Duration Near-Nozzle Mixing for 3D Concrete Printing

55 Citations

  1. Skoury Lior, Asaf Ofer, Sprecher Aaron, Menges Achim et al. (2025-12)
    Data-Informed Digital Twin for Large-Scale 3D Printing in Construction
  2. Athira R., Sathyan Dhanya (2025-11)
    Review of 3D Printing Advancements in Geopolymer Concrete:
    Current Challenges and Future Directions
  3. Tang Jiyu, Wang Zhihang, Gao Danying, Yang Lin et al. (2025-11)
    Research Progress on 3D Printed Geopolymer Concrete
  4. Shekhar Shashank, Kumar Manish, Mathur Rishabh (2025-10)
    Additive Manufacturing of Concrete with Low Initial Yield Strength Through Controlled Heating of Printed Layers
  5. Elhag Ahmed, Mabrouk Abdelkader, Ghazouani Nejib, Nasir Umara (2025-09)
    Advances in Sustainable 3D-Printed Geopolymer Concrete:
    Materials, Performance, and Environmental Impact in Next Generation Green Construction
  6. Ramirez Rodriguez Fatima, Ahmad Rafiq (2025-09)
    Sustainable Technology Advances for Additive Construction:
    A State-of-the-Art Review
  7. Rajeev Pathmanathan, Kopitha Kirushnapillai, Sanjayan Jay (2025-06)
    Carbonated Water and MgO for Improved Performance of 3D Concrete Printing.
  8. Lin Wenyu, Wang Li, Li Zhijian, Bai Gang et al. (2025-06)
    Multi-Scale Fabrication and Challenges in 3D Printing of Special -Shaped Concrete Structures
  9. Jaji Mustapha, Babafemi Adewumi, Zijl Gideon (2025-05)
    Mechanical Performance of Extrusion-Based Two-Part 3D-Printed Geopolymer Concrete:
    A Review of Advances in Laboratory and Real-Scale Construction Projects
  10. Mishra Sanjeet, Snehal K., Das B., Chandrasekaran Rajasekaran et al. (2025-05)
    From Printing to Performance:
    A Review on 3D Concrete Printing Processes, Materials, and Life Cycle Assessment
  11. Tanyildizi Harun, Seloglu Maksut, Bakri Abdullah Mohd, Razak Rafiza et al. (2025-04)
    The Rheological and Mechanical Properties of 3D-Printed Geopolymers:
    A Review
  12. Ali Shah Syed, Zhang Shipeng, Xuan Dongxing, Poon Chi (2025-04)
    Development of a Novel Mixing Strategy for Set-on-Demand Printing of One-Part Geopolymer Using Municipal Solid Waste Incineration Bottom Ash and Blast Furnace Slag
  13. Abudawaba Fareh, Gomaa Eslam, Gheni Ahmed, Feys Dimitri et al. (2025-03)
    Evaluation of Fresh Properties of High Calcium Content Fly Ash-Based Alkali-Activated 3D-Printed Mortar
  14. Tanyildizi Harun, Coskun Ahmet, Seloglu Maksut, Durmaz Taner (2025-01)
    Examination of Mechanical Properties of 3D Printed Geopolymer-Mortar Using the Taguchi -Method
  15. Sakhare Vishakha, Najar Mohamed, Deshpande Sachin (2024-12)
    Printing Performance of 3D Printed Geopolymer Through Pumpability, Extrudability, Buildability Properties:
    A Review
  16. Maroszek Marcin, Rudziewicz Magdalena, Hutyra Adam, Dziura Paweł et al. (2024-12)
    Evaluation of 3D Concrete Printing Extrusion-Efficiency
  17. Sahoo Pitabash, Gupta Souradeep (2024-11)
    3D Printing with Geopolymer-Stabilized Excavated Earth:
    Enhancement of Printability and Engineering-Performance Through Controlled Retardation
  18. Habibi Alireza, Buswell Richard, Osmani Mohamed, Aziminezhad Mohamadmahdi (2024-11)
    Sustainability Principles in 3D Concrete Printing:
    Analysing Trends, Classifying Strategies, and Future Directions
  19. Wang Xianggang, Dong Enlai, Jia Zijian, Jia Lutao et al. (2024-09)
    Specimen-Size-Effect on Compressive Strength of 3D Printed Concrete Containing Coarse Aggregate with Varying Water-to-Binder-Ratios
  20. Perrot Arnaud, Jacquet Yohan, Caron Jean-François, Mesnil Romain et al. (2024-08)
    Snapshot on 3D Printing with Alternative Binders and Materials:
    Earth, Geopolymers, Gypsum and Low-Carbon Concrete
  21. Wangler Timothy, Tao Yaxin, Das Arnesh, Mahmoudi Matineh et al. (2024-08)
    Aluminate 2K Systems in Digital Concrete:
    Process, Design, Chemistry, and Outlook
  22. Aghaee Kamran, Li Linfei, Roshan Alireza, Namakiaraghi Parsa (2024-08)
    Additive Manufacturing Evolution in Construction:
    From Individual Terrestrial to Collective, Aerial, and Extraterrestrial Applications
  23. Muthukrishnan Shravan, Ramakrishnan Sayanthan, Sanjayan Jay (2024-07)
    Set-on-Demand Geopolymer for Concrete 3D Printing Using Ternary Activator
  24. Ramesh Akilesh, Rajeev Pathmanathan, Sanjayan Jay (2024-07)
    Application of Textile Reinforcement for 3D Concrete Printed Structures
  25. Barve Prasad, Bahrami Alireza, Shah Santosh (2024-07)
    A Comprehensive Review on Effects of Material-Composition, Mix-Design, and Mixing-Regimes on Rheology of 3D Printed Geopolymer Concrete
  26. Krishna R., Rehman Asif, Mishra Jyotirmoy, Saha Suman et al. (2024-06)
    Additive Manufacturing of Geopolymer Composites for Sustainable Construction:
    Critical Factors, Advancements, Challenges, and Future Directions
  27. Kanagasuntharam Sasitharan, Ramakrishnan Sayanthan, Sanjayan Jay (2024-06)
    Encapsulation of Sodium-Silicate to Attain on Demand Buildability Enhancement in Concrete 3D Printing
  28. Rama Krishna A., Mallik Mainak, Maity Damodar (2024-06)
    Developing an Appropriate Concrete Mix for 3D Concrete Printing
  29. Ramesh Akilesh, Rajeev Pathmanathan, Sanjayan Jay, Mechtcherine Viktor (2024-06)
    In-Process Textile Reinforcement Method for 3D Concrete Printing and Its Structural Performance
  30. Birru Bizu, Rehman Atta, Kim Jung-Hoon (2024-06)
    Comparative Analysis of Structural Build-Up in One-Component Stiff and Two-Component Shotcrete-Accelerated Set-on-Demand Mixtures for 3D Concrete Printing
  31. Ramakrishnan Sayanthan, Pasupathy Kirubajiny, Mechtcherine Viktor, Sanjayan Jay (2024-05)
    Print-Head Mixing of Geopolymer and OPC Slurries for Hybrid Alkali-Activated Cement in 3D Concrete Printing
  32. Tao Yaxin, Yuan Yong (2024-05)
    3D Concrete Printing for Tunnel Linings:
    Opportunities and Challenges
  33. Sheng Zhaoliang, Zhu Binrong, Cai Jingming, Li Xuesen et al. (2024-03)
    Development of a Novel Extrusion-Device to Improve the Printability of 3D Printable Geopolymer Concrete
  34. Liu Xinhao, Hu Jiajun, Guo Xiaolu (2024-03)
    Printability and Inter-Layer Bonding Property of 3D Printed Fiber-Reinforced Geopolymer
  35. Ziada Mahmoud, Tanyildizi Harun, Seloglu Maksut, Coskun Ahmet (2024-02)
    Bacteria-Based Crack-Healing of 3D Printed PVA-Fiber-Reinforced Geopolymer Mortars
  36. Moraes Maria, Nagata Ester, Duran Afonso, Rossignolo João (2024-02)
    Alkali-Activated Materials Applied in 3D Printing Construction:
    A Review
  37. Ramesh Akilesh, Rajeev Pathmanathan, Sanjayan Jay (2024-02)
    Bond-Slip Behavior of Textile-Reinforcement in 3D Printed Concrete
  38. Zhang Hanghua, Tan Yanke, Hao Lucen, Zheng Shipeng et al. (2024-02)
    Intelligent Real-Time Quality-Control for 3D Printed Concrete with Near-Nozzle Secondary-Mixing
  39. Chen Kailun, Liu Qiong, Chen Bing, Zhang Shishun et al. (2024-01)
    A Review on Effect of Raw Materials on the Performance of 3D Printed Geopolymer System for Construction
  40. Kanagasuntharam Sasitharan, Ramakrishnan Sayanthan, Sanjayan Jay (2023-10)
    Investigating PCM Encapsulated NaOH Additive for Set-on-Demand in 3D Concrete Printing
  41. Muthukrishnan Shravan, Ramakrishnan Sayanthan, Sanjayan Jay (2023-09)
    Rapid Early-Age Strength Development of In-Line Activated Geopolymer for Concrete 3D Printing
  42. Shilar Fatheali, Ganachari Sharanabasava, Patil Veerabhadragouda, Bhojaraja B. et al. (2023-08)
    A Review of 3D Printing of Geopolymer Composites for Structural and Functional Applications
  43. Jaji Mustapha, Zijl Gideon, Babafemi Adewumi (2023-08)
    Slag-Modified Fiber-Reinforced Metakaolin-Based Geopolymer for 3D Concrete Printing Application:
    Evaluating Fresh and Hardened Properties
  44. Wang Chaofan, Chen Bing, Vo Thanh, Rezania Mohammad (2023-07)
    Mechanical Anisotropy, Rheology and Carbon Footprint of 3D Printable Concrete:
    A Review
  45. Riaz Raja, Usman Muhammad, Ali Ammar, Majid Usama et al. (2023-06)
    Inclusive Characterization of 3D Printed Concrete in Additive Manufacturing:
    A Detailed Review
  46. Tao Yaxin, Dai Xiaodi, Schutter Geert, Tittelboom Kim (2023-06)
    Set-on-Demand of Alkali-Activated Slag Mixture Using Twin-Pipe Pumping
  47. Mujeeb Syed, Samudrala Manideep, Lanjewar Bhagyashri, Chippagiri Ravijanya et al. (2023-05)
    Development of Alkali-Activated 3D Printable Concrete:
    A Review
  48. Kanagasuntharam Sasitharan, Ramakrishnan Sayanthan, Muthukrishnan Shravan, Sanjayan Jay (2023-05)
    Effect of Magnetorheological Additives on the Buildability of 3D Concrete Printing
  49. Dias Bruno, Rocha Douglas, Faria Paulina, Lucas Sandra et al. (2023-04)
    Limes with Hydraulic Properties for 3D Printing Mortars
  50. Quah Tan, Tay Yi, Lim Jian, Tan Ming et al. (2023-03)
    Concrete 3D Printing:
    Process-Parameters for Process-Control, Monitoring and Diagnosis in Automation and Construction
  51. Arunothayan Arun, Sanjayan Jay (2023-01)
    Elevated Temperature Effects on 3D Printed Ultra-High-Performance Concrete
  52. Dahlenburg Maximilian, Hechtl Christian, Matthäus Carla, Fottner Johannes (2022-11)
    3D Concrete Printing:
    Graded Concrete-Extrusion
  53. Muthukrishnan Shravan, Ramakrishnan Sayanthan, Sanjayan Jay (2022-10)
    In-Line Activation of Geopolymer-Slurry for Concrete 3D Printing
  54. Kaliyavaradhan Senthil, Ambily Parukutty, Prem Prabhat, Ghodke Swapnil (2022-08)
    Test-Methods for 3D Printable Concrete
  55. Ziejewska Celina, Marczyk Joanna, Korniejenko Kinga, Bednarz Sebastian et al. (2022-04)
    3D Printing of Concrete-Geopolymer Hybrids

BibTeX
@article{muth_rama_sanj.2022.SoDGUPHMf3CP,
  author            = "Shravan Muthukrishnan and Sayanthan Ramakrishnan and Jay Gnananandan Sanjayan",
  title             = "Set-on-Demand Geopolymer Using Print-Head Mixing for 3D Concrete Printing",
  doi               = "10.1016/j.cemconcomp.2022.104451",
  year              = "2022",
  journal           = "Cement and Concrete Composites",
  volume            = "128",
}
Formatted Citation

S. Muthukrishnan, S. Ramakrishnan and J. G. Sanjayan, “Set-on-Demand Geopolymer Using Print-Head Mixing for 3D Concrete Printing”, Cement and Concrete Composites, vol. 128, 2022, doi: 10.1016/j.cemconcomp.2022.104451.

Muthukrishnan, Shravan, Sayanthan Ramakrishnan, and Jay Gnananandan Sanjayan. “Set-on-Demand Geopolymer Using Print-Head Mixing for 3D Concrete Printing”. Cement and Concrete Composites 128 (2022). https://doi.org/10.1016/j.cemconcomp.2022.104451.