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A Review of 3D Printing of Geopolymer Composites for Structural and Functional Applications (2023-08)

10.1016/j.conbuildmat.2023.132869

 Shilar Fatheali,  Ganachari Sharanabasava,  Patil Veerabhadragouda, Bhojaraja B., Yunus Khan T., Almakayeel Naif
Journal Article - Construction and Building Materials, Vol. 400, No. 132869

Abstract

The 3D printing allows for the automated and quick building of structures, drastically reducing the time and labour necessary for traditional construction methods. An extensive analysis of more than 100 + articles aimed to present a thorough summary of the present research status on 3D printing of geopolymer substances, investigating different factors, including printing methods, material traits, and geopolymerization procedures. The fresh and mechanical properties result of 3D geopolymer composites are reviewed and represented in kernel density, radar, quantile–quantile plots, and multi-Y analysis plots for various binder ratios. The effect of Si/Al, activators, and factors that influence the acceleration of geopolymerization of 3D-based geopolymers is discussed. Different types of 3D printing machines, along with layer adhesion thixotropy and its relation to printability, printing speed, adhesion of layers, and storage condition, are studied, as are their mechanisms. Using pozzolanic materials in the chemical reaction between quicklime and silicate materials enhances the structural performance of the geopolymer material, resulting in superior properties. This review's findings and suggestions attempt to lay the foundation for future study in this field, which offers assistance in building 3D-printed composite materials with the necessary sustainability.

62 References

  1. Ahmed Ghafur (2023-01)
    A Review of 3D Concrete Printing:
    Materials and Process Characterization, Economic Considerations and Environmental Sustainability
  2. Ahmed Ghafur, Askandar Nasih, Jumaa Ghazi (2022-07)
    A Review of Large-Scale 3DCP:
    Material-Characteristics, Mix-Design, Printing-Process, and Reinforcement-Strategies
  3. Alabbasi Mohammad, Agkathidis Asterios, Chen Hanmei (2023-01)
    Robotic 3D Printing of Concrete Building Components for Residential Buildings in Saudi Arabia
  4. Aramburu Amaia, Calderon-Uriszar-Aldaca Iñigo, Puente Iñigo (2022-09)
    3D Printing Effect on the Compressive Strength of Concrete Structures
  5. Biricik Öznur, Mardani Ali (2022-05)
    Parameters Affecting Thixotropic Behavior of Self-Compacting Concrete and 3D Printable Concrete:
    A State of the Art Review
  6. Bong Shin, Nematollahi Behzad, Xia Ming, Ghaffar Seyed et al. (2022-04)
    Properties of Additively Manufactured Geopolymer Incorporating Mineral-Wollastonite-Micro-Fibers
  7. Chen Wei, Pan Jinlong, Zhu Binrong, Ma XiaoMeng et al. (2023-06)
    Improving Mechanical Properties of 3D Printable One-Part Geopolymer Concrete with Steel-Fiber-Reinforcement
  8. Chougan Mehdi, Ghaffar Seyed, Jahanzat Mohammad, Albar Abdulrahman et al. (2020-04)
    The Influence of Nano-Additives in Strengthening Mechanical Performance of 3D Printed Multi-Binder Geopolymer Composites
  9. Chougan Mehdi, Ghaffar Seyed, Sikora Paweł, Chung Sang-Yeop et al. (2021-02)
    Investigation of Additive Incorporation on Rheological, Microstructural and Mechanical Properties of 3D Printable Alkali-Activated Materials
  10. Chun Seung-Yeop, Kim Su-jin, Kim Woon-Gi, Lee Geumyeon et al. (2022-12)
    Powder-Bed-Based 3D Printing with Cement for Sustainable Casting
  11. Demiral Nazim, Ozkan Ekinci Mehmet, Şahin Oğuzhan, İlcan Hüseyin et al. (2022-10)
    Mechanical Anisotropy Evaluation and Bonding Properties of 3D Printable Construction and Demolition Waste-Based Geopolymer Mortars
  12. Dey Dhrutiman, Srinivas Dodda, Panda Biranchi, Suraneni Prannoy et al. (2022-02)
    Use of Industrial Waste-Materials for 3D Printing of Sustainable Concrete:
    A Review
  13. Heidarnezhad Fatemeh, Zhang Qian (2022-01)
    Shotcrete-Based 3D Concrete Printing:
    State of Art, Challenges, and Opportunities
  14. Huang Xin, Yang Weihao, Song Fangnian, Zou Jiuqun (2022-04)
    Study on the Mechanical Properties of 3D Printing Concrete Layers and the Mechanism of Influence of Printing Parameters
  15. İlcan Hüseyin, Şahin Oğuzhan, Kul Anil, Ozcelikci Emircan et al. (2022-12)
    Rheological Property and Extrudability Performance-Assessment of Construction and Demolition Waste-Based Geopolymer Mortars with Varied Testing Protocols
  16. İlcan Hüseyin, Şahin Oğuzhan, Kul Anil, Yıldırım Gürkan et al. (2022-03)
    Rheological Properties and Compressive Strength of Construction and Demolition Waste-Based Geopolymer Mortars for 3D Printing
  17. Kaliyavaradhan Senthil, Ambily Parukutty, Prem Prabhat, Ghodke Swapnil (2022-08)
    Test-Methods for 3D Printable Concrete
  18. Kamel Ehsan, Kazemian Ali (2022-11)
    BIM-Integrated Thermal Analysis and Building Energy Modeling in 3D Printed Residential Buildings
  19. Khan Shoukat, İlcan Hüseyin, Aminipour Ehsan, Şahin Oğuzhan et al. (2023-07)
    Buildability-Analysis on Effect of Structural Design in 3D Concrete Printing:
    An Experimental and Numerical Study
  20. Khan Shoukat, Jassim Muhammad, İlcan Hüseyin, Şahin Oğuzhan et al. (2023-04)
    3D Printing of Circular Materials:
    Comparative Environmental Analysis of Materials and Construction Techniques
  21. Khan Shoukat, Koç Muammer (2022-10)
    Numerical Modelling and Simulation for Extrusion-Based 3D Concrete Printing:
    The Underlying Physics, Potential, and Challenges
  22. Khosravani Mohammad, Haghighi Azadeh (2022-08)
    Large-Scale Automated Additive Construction:
    Overview, Robotic Solutions, Sustainability, and Future Prospect
  23. Klyuev Sergey, Klyuev Alexander, Fediuk Roman, Ageeva Marina et al. (2022-04)
    Fresh and Mechanical Properties of Low-Cement Mortars for 3D Printing
  24. Kondepudi Kala, Subramaniam Kolluru, Nematollahi Behzad, Bong Shin et al. (2022-05)
    Study of Particle-Packing and Paste-Rheology in Alkali-Activated Mixtures to Meet the Rheology Demands of 3D Concrete Printing
  25. Kondepudi Kala, Subramaniam Kolluru, Nematollahi Behzad, Bong Shin et al. (2022-11)
    Study of Particle-Packing and Paste-Rheology in Alkali-Activated Mixtures to Meet the Rheology Demands of 3D Concrete Printing:
    Correction
  26. Li Zhengrong, Xing Wenjing, Sun Jingting, Feng Xiwen (2022-12)
    Multi-Scale Structural Characteristics and Heat-Moisture Properties of 3D Printed Building Walls:
    A Review
  27. Liu Bing, Liu Xiaoyan, Li Guangtao, Geng Songyuan et al. (2022-09)
    Study on Anisotropy of 3D Printing PVA-Fiber-Reinforced Concrete Using Destructive and Non-Destructive Testing Methods
  28. Lowke Dirk, Dini Enrico, Perrot Arnaud, Weger Daniel et al. (2018-07)
    Particle-Bed 3D Printing in Concrete Construction:
    Possibilities and Challenges
  29. Lu Bing, Li Hongliang, Li Mingyang, Wong Teck et al. (2022-11)
    Mechanism and Design of Fluid Catalytic Cracking Ash-Blended Cementitious Composites for High-Performance Printing
  30. Ma Guowei, Li Zhijian, Wang Li, Wang Fang et al. (2019-01)
    Mechanical Anisotropy of Aligned Fiber-Reinforced Composite for Extrusion-Based 3D Printing
  31. Ma Guowei, Yan Yufei, Zhang Mo, Sanjayan Jay (2022-05)
    Effect of Steel-Slag on 3D Concrete Printing of Geopolymer with Quaternary Binders
  32. Mesnil Romain, Poussard Valentin, Sab Karam, Caron Jean-François (2022-11)
    On the Geometrical Origin of the Anisotropy in Extrusion-Based 3D Printed Structures
  33. Mir Namra, Khan Shoukat, Kul Anil, Şahin Oğuzhan et al. (2022-08)
    Life Cycle Assessment of Construction and Demolition Waste-Based Geopolymers Suited for Use in 3D Additive Manufacturing
  34. Mortada Youssef, Masad Eyad, Kogbara Reginald, Mansoor Bilal et al. (2023-06)
    Development of Ca(OH)2-Based Geopolymer for Additive Manufacturing Using Construction Wastes and Nano-Materials
  35. Muthukrishnan Shravan, Ramakrishnan Sayanthan, Sanjayan Jay (2022-10)
    In-Line Activation of Geopolymer-Slurry for Concrete 3D Printing
  36. Muthukrishnan Shravan, Ramakrishnan Sayanthan, Sanjayan Jay (2022-02)
    Set-on-Demand Geopolymer Using Print-Head Mixing for 3D Concrete Printing
  37. Noaimat Yazeed, Ghaffar Seyed, Chougan Mehdi, Kheetan Mazen (2022-12)
    A Review of 3D Printing Low-Carbon Concrete with One-Part Geopolymer:
    Engineering, Environmental and Economic Feasibility
  38. Nodehi Mehrab, Aguayo Federico, Nodehi Shahab, Gholampour Aliakbar et al. (2022-07)
    Durability Properties of 3D Printed Concrete
  39. Nodehi Mehrab, Ozbakkaloglu Togay, Gholampour Aliakbar (2022-04)
    Effect of Supplementary Cementitious Materials on Properties of 3D Printed Conventional and Alkali-Activated Concrete:
    A Review
  40. Panda Biranchi, Paul Suvash, Lim Jian, Tay Yi et al. (2017-08)
    Additive Manufacturing of Geopolymer for Sustainable Built Environment
  41. Panda Biranchi, Paul Suvash, Mohamed Nisar, Tay Yi et al. (2017-09)
    Measurement of Tensile Bond Strength of 3D Printed Geopolymer Mortar
  42. Panda Biranchi, Unluer Cise, Tan Ming (2019-08)
    Extrusion and Rheology Characterization of Geopolymer Nanocomposites Used in 3D Printing
  43. Pasupathy Kirubajiny, Ramakrishnan Sayanthan, Sanjayan Jay (2023-01)
    3D Concrete Printing of Eco-Friendly Geopolymer Containing Brick Waste
  44. Peng Yiming, Unluer Cise (2022-12)
    Development of Alternative Cementitious Binders for 3D Printing Applications:
    A Critical Review of Progress, Advantages and Challenges
  45. Qaidi Shaker, Yahia Ammar, Tayeh B., Unis H. et al. (2022-10)
    3D Printed Geopolymer Composites:
    A Review
  46. Rahemipoor Sahand, Hasany Masoud, Mehrali Mohammad, Almdal Kristoffer et al. (2023-07)
    Phase-Change-Materials Incorporation into 3D Printed Geopolymer Cement:
    A Sustainable Approach to Enhance the Comfort and Energy Efficiency of Buildings
  47. Raza Muhammad, Zhong Ray (2022-08)
    A Sustainable Roadmap for Additive Manufacturing Using Geopolymers in Construction Industry
  48. Robayo-Salazar Rafael, Gutiérrez Ruby, Villaquirán-Caicedo Mónica, Delvasto Arjona Silvio (2022-12)
    3D Printing with Cementitious Materials:
    Challenges and Opportunities for the Construction Sector
  49. Şahin Hatice, Mardani Ali (2021-12)
    Assessment of Materials, Design Parameters and Some Properties of 3D Printing Concrete Mixtures:
    A State of the Art Review
  50. Salaimanimagudam M., Jayaprakash Jaganathan (2022-11)
    Optimum Selection of Reinforcement, Assembly, and Formwork System for Digital Fabrication Technique in Construction Industry:
    A Critical Review
  51. Saruhan Vedat, Keskinateş Muhammer, Felekoğlu Burak (2022-04)
    A Comprehensive Review on Fresh State Rheological Properties of Extrusion-Mortars Designed for 3D Printing Applications
  52. Teixeira João, Schaefer Cecília, Rangel Bárbara, Maia Lino et al. (2022-11)
    A Road Map to Find in 3D Printing a New Design Plasticity for Construction:
    The State of Art
  53. Tinoco Matheus, Gouvêa Lucas, Cássia Magalhães Martins Karenn, Toledo Filho Romildo et al. (2022-12)
    The Use of Rice Husk Particles to Adjust the Rheological Properties of 3D Printable Cementitious Composites Through Water Sorption
  54. Tinoco Matheus, Mendonça Érica, Fernandez Letízia, Caldas Lucas et al. (2022-04)
    Life Cycle Assessment and Environmental Sustainability of Cementitious Materials for 3D Concrete Printing:
    A Systematic Literature Review
  55. Tran Mien, Vu Tran, Nguyen Thi (2023-01)
    Simplified Assessment for One-Part 3D Printable Geopolymer Concrete Based on Slump and Slump-Flow Measurements
  56. Ulubeyli Serdar (2022-03)
    Lunar Shelter Construction Issues:
    The State of the Art Towards 3D Printing Technologies
  57. Xu Weiguo, Huang Shuyi, Han Dong, Zhang Zhiling et al. (2022-08)
    Toward Automated Construction:
    The Design-to-Printing Workflow for a Robotic In-Situ 3D Printed House
  58. Xu Zhuoyue, Zhang Dawang, Li Hui, Sun Xuemei et al. (2022-05)
    Effect of FA and GGBFS on Compressive Strength, Rheology, and Printing Properties of Cement-Based 3D Printing Material
  59. Yang Yekai, Wu Chengqing, Liu Zhongxian, Li Jun et al. (2022-02)
    Characteristics of 3D Printing Ultra-High-Performance Fiber-Reinforced Concrete Under Impact Loading
  60. Yoris-Nobile Adrian, Slebi-Acevedo Carlos, Lizasoain-Arteaga Esther, Indacoechea-Vega Irune et al. (2022-11)
    Artificial Reefs Built by 3D Printing:
    Systematisation in the Design, Material-Selection and Fabrication
  61. Zhong Hui, Zhang Mingzhong (2022-02)
    3D Printing Geopolymers:
    A Review
  62. Zhou Longfei, Gou Mifeng, Zhang Haibo (2022-12)
    Investigation on the Applicability of Bauxite-Tailings as Fine Aggregate to Prepare 3D Printing Mortar

34 Citations

  1. Driouich Anas, Dalconi Maria, Franchin Giorgia, Bettanini Carlo et al. (2026-01)
    Optimization of Alkali-Activated Regolith Simulants for Lunar Construction by 3D Printing
  2. Murali Gunasekaran, Kravchenko Ekaterina, Yuvaraj Divya, Avudaiappan Siva (2025-12)
    Next-Generation Green Construction:
    3D-Printed Geopolymer Concrete with Optimized Rheology, Mechanical Performance, and Environmental Efficiency
  3. Iqbal Imtiaz, Kasim Tala, Besklubova Svetlana, Inqiad Waleed et al. (2025-12)
    Exploring Knowledge Domains and Future Research Directions in 3D Printed Concrete:
    A Bibliometric and Systematic Review
  4. Athira R., Sathyan Dhanya (2025-11)
    Review of 3D Printing Advancements in Geopolymer Concrete:
    Current Challenges and Future Directions
  5. Hasan Md, Xu Jie, Uddin Md (2025-11)
    A Critical Review of 3D Printed Fiber-Based Geopolymer Concrete:
    Fresh Properties, Mechanical Performance, and Current Limitations
  6. Tang Jiyu, Wang Zhihang, Gao Danying, Yang Lin et al. (2025-11)
    Research Progress on 3D Printed Geopolymer Concrete
  7. Uddin Md, Mostazid Md, Faysal Md, Shi Xinjun (2025-10)
    Developing a Novel Strength Predictive Modeling for 3D Printable Geopolymer Concrete:
    An Interpretable Data-Driven Approach
  8. Rudziewicz Magdalena, Maroszek Marcin, Hebda Marek (2025-09)
    Comparison of Porosity and Thermal Conductivity of Concrete and Alkali-Activated Hybrid Binders in 3D-Printed Fiber-Reinforced Foamed Composites
  9. Elhag Ahmed, Mabrouk Abdelkader, Ghazouani Nejib, Nasir Umara (2025-09)
    Advances in Sustainable 3D-Printed Geopolymer Concrete:
    Materials, Performance, and Environmental Impact in Next Generation Green Construction
  10. Liu Ruiying, Xiong Zhongming, Chen Xuan, Jia Qiong et al. (2025-09)
    Industrial Waste in 3D Printed Concrete:
    A Mechanistic Review on Rheological Control and Printability
  11. Banihashemi Saeed, Akbarnezhad Ali, Sheikhkhoshkar Moslem, Haouzi Hind et al. (2025-08)
    3D Printing in Construction:
    Sustainable Technology for Building Industry
  12. Wang Jiakang, Anwar Muhammad, Zhu Xingyi, Zhang Yating et al. (2025-07)
    Robust Optimization of Formulation Ratios for the Mechanical, Microstructural and Printing Performance of Cost-Effective 3D Printing Geopolymer
  13. Zhang Chao, Ren Juanjuan, Zhang Shihao, Guo Yipu et al. (2025-07)
    Advanced Impact Resistance Design Through 3D-Printed Concrete Technology:
    Unleashing the Potential of Additive Manufacturing for Protective Structures
  14. Du Shizhao, Kang Chunxia, Du Xiuli (2025-06)
    Fatigue Performance of 3D Printed Reusable Concrete Slabs for Temporary Pavements
  15. Alkhawaldeh Ayah, Alhassan Mohammad, Sawalha Ansam, Betoush Nour et al. (2025-06)
    Integration of 3D Printing and Machine Learning in Sustainable Construction:
    Feasibility and Challenges
  16. Sakhare Vishakha, Khairnar Neha, Dahatonde Ulka, Mashalkar Shilpa (2025-06)
    Review on Sustainability in 3D Concrete Printing:
    Focus on Waste Utilization and Life Cycle Assessment
  17. Ye Chengjie, Xu Jie, Lacidogna Giuseppe (2025-06)
    Fracture Behavior of 3D Printed Geopolymer Concrete Containing Waste Ceramic
  18. Girskas Giedrius, Kligys Modestas (2025-06)
    3D Concrete Printing Review:
    Equipment, Materials, Mix Design, and Properties
  19. Raza Ali, Junjie Zhang, Fan Jiahui, Umar Muhammad et al. (2025-05)
    Comprehensive Study on the Microstructural and Mechanical Performance of 3D-Printed Engineered Cementitious Composites with Yellow River Sand Integration
  20. Jaji Mustapha, Babafemi Adewumi, Zijl Gideon (2025-05)
    Mechanical Performance of Extrusion-Based Two-Part 3D-Printed Geopolymer Concrete:
    A Review of Advances in Laboratory and Real-Scale Construction Projects
  21. Becher Anton, Gądek Szymon, Korniejenko Kinga (2025-05)
    3D Printing with Geopolymers and Its Applications
  22. Mishra Jyotirmoy, Babafemi Adewumi, Combrinck Riaan (2025-04)
    Limitations and Research Priorities in 3D-Printed Geopolymer Concrete:
    A Perspective Contribution
  23. Tanyildizi Harun, Seloglu Maksut, Bakri Abdullah Mohd, Razak Rafiza et al. (2025-04)
    The Rheological and Mechanical Properties of 3D-Printed Geopolymers:
    A Review
  24. İlcan Hüseyin, Külak Adnan, Şahin Oğuzhan, Aldemir Alper et al. (2025-04)
    Reinforcement and Modular System for 3DCP Geopolymer Structures Using Construction and Demolition Waste
  25. Hassan Amer, Alomayri Thamer, Noaman Mohammed, Zhang Chunwei (2025-01)
    3D Printed Concrete for Sustainable Construction:
    A Review of Mechanical Properties and Environmental Impact
  26. Sakhare Vishakha, Najar Mohamed, Deshpande Sachin (2024-12)
    Printing Performance of 3D Printed Geopolymer Through Pumpability, Extrudability, Buildability Properties:
    A Review
  27. Silvestro Laura, Ribeiro Rodrigo, Navarrete Iván (2024-12)
    Advancements in Low Carbon-Emission Cements for 3D Printing:
    A State-of-the-Art Review
  28. Perrot Arnaud, Jacquet Yohan, Caron Jean-François, Mesnil Romain et al. (2024-08)
    Snapshot on 3D Printing with Alternative Binders and Materials:
    Earth, Geopolymers, Gypsum and Low-Carbon Concrete
  29. Hutyra Adam, Bańkosz Magdalena, Tyliszczak Bożena (2024-08)
    Technology for Automated Production of High-Performance Building Compounds for 3D Printing
  30. Zhong Kuangnan, Huang Kaiyun, Liu Zhichao, Wang Fazhou et al. (2024-07)
    CO2-Driven Additive Manufacturing of Sustainable Steel-Slag-Mortars
  31. Zhou Zhijie, Geng Jian, Jin Chen, Liu Genjin et al. (2024-06)
    Influence of Residue Soil on the Properties of Fly-Ash-Slag-Based Geopolymer Materials for 3D Printing
  32. Hassan Habibelrahman, Rodriguez-Ubinas Edwin, Tamimi Adil, Trepci Esra et al. (2024-04)
    Towards Innovative and Sustainable Buildings:
    A Comprehensive Review of 3D Printing in Construction
  33. Chen Kailun, Liu Qiong, Chen Bing, Zhang Shishun et al. (2024-01)
    A Review on Effect of Raw Materials on the Performance of 3D Printed Geopolymer System for Construction
  34. Fiala Lukáš, Lin Wei-Ting, Hotěk Petr, Cheng An (2023-11)
    Feasibility Study of Developing Cementless Blended Materials as 3D Printable Materials

BibTeX
@article{shil_gana_pati_bhoj.2023.ARo3PoGCfSaFA,
  author            = "Fatheali A. Shilar and Sharanabasava V. Ganachari and Veerabhadragouda B. Patil and B. E. Bhojaraja and T. M. Yunus Khan and Naif Almakayeel",
  title             = "A Review of 3D Printing of Geopolymer Composites for Structural and Functional Applications",
  doi               = "10.1016/j.conbuildmat.2023.132869",
  year              = "2023",
  journal           = "Construction and Building Materials",
  volume            = "400",
  pages             = "132869",
}
Formatted Citation

F. A. Shilar, S. V. Ganachari, V. B. Patil, B. E. Bhojaraja, T. M. Y. Khan and N. Almakayeel, “A Review of 3D Printing of Geopolymer Composites for Structural and Functional Applications”, Construction and Building Materials, vol. 400, p. 132869, 2023, doi: 10.1016/j.conbuildmat.2023.132869.

Shilar, Fatheali A., Sharanabasava V. Ganachari, Veerabhadragouda B. Patil, B. E. Bhojaraja, T. M. Yunus Khan, and Naif Almakayeel. “A Review of 3D Printing of Geopolymer Composites for Structural and Functional Applications”. Construction and Building Materials 400 (2023): 132869. https://doi.org/10.1016/j.conbuildmat.2023.132869.