Skip to content

Effects of Additives on the Mechanical Properties, Rheology, and Printing Properties of PCC-Based 3DPMs (2023-06)

10.1016/j.ceramint.2023.06.090

Xu Zhuoyue,  Zhang Dawang,  Li Hui, Yin Le, Song Haiping, Wang Wanchun, Zhang Siyu
Journal Article - Ceramics International

Abstract

A study was performed on printing concrete made with Portland cement clinker (Pcc) (the base material), quartz sand (the aggregate), a water reducer, and the additives hydroxypropyl methyl cellulose ether (HMC), redispersible latex powder (RLP), lithium carbonate (LC) and triethanolamine (TEA) were used to adjust the material properties. A clinker-based 3D printing material exhibiting excellent rheology, extrudability, buildability, and mechanical properties was developed. Admixture incorporation decreased the spread and slump of the Pcc while improving the rheological properties (G’, G’’, |η*|, and the torque). The addition of HMC and appropriate quantities of RLP and LC increased the slump and expansion of the cement paste, but the addition of TEA had adverse effects on the slump and expansion of the slurry paste. The admixture decreased the setting time of the Pcc slurry, and the effect decreased in the order TEA, LC, RLP, and HMC. The admixture also degraded the mechanical properties of the slurry. The use of a D-2 mix design consisting of 0.25% HMC, 0.20% RLP, 0.08% LC, and 0.010% TEA resulted in the maximum extrusion length of the printed sample, 90 mm, and the maximum number of printing layers, 32. SEM images showed that the main hydration products were calcium silicate hydrate (C–S–H) and calcium hydroxide (CH). The admixture mainly affected the early performance of the samples and had little influence on the late performance. This result was consistent with those obtained from hydration tests on Pcc. A reaction model for the addition of an admixture to a Pcc slurry was proposed.

33 References

  1. Asprone Domenico, Menna Costantino, Bos Freek, Salet Theo et al. (2018-06)
    Rethinking Reinforcement for Digital Fabrication with Concrete
  2. Chen Yu, Figueiredo Stefan, Yalçınkaya Çağlar, Çopuroğlu Oğuzhan et al. (2019-04)
    The Effect of Viscosity-Modifying Admixture on the Extrudability of Limestone and Calcined-Clay-Based Cementitious Material for Extrusion-Based 3D Concrete Printing
  3. Chen Yu, He Shan, Zhang Yu, Wan Zhi et al. (2021-08)
    3D Printing of Calcined-Clay-Limestone-Based Cementitious Materials
  4. Chen Mingxu, Li Laibo, Wang Jiaao, Huang Yongbo et al. (2019-10)
    Rheological Parameters and Building Time of 3D Printing Sulphoaluminate-Cement-Paste Modified by Retarder and Diatomite
  5. Ding Tao, Xiao Jianzhuang, Qin Fei, Duan Zhenhua (2020-03)
    Mechanical Behavior of 3D Printed Mortar with Recycled Sand at Early-Ages
  6. Falliano Devid, Domenico Dario, Ricciardi Giuseppe, Gugliandolo Ernesto (2020-04)
    3D Printable Lightweight Foamed Concrete and Comparison with Classical Foamed Concrete in Terms of Fresh State Properties and Mechanical Strength
  7. Figueiredo Stefan, Rodríguez Claudia, Ahmed Zeeshan, Bos Derk et al. (2019-03)
    An Approach to Develop Printable Strain-Hardening Cementitious Composites
  8. Gosselin Clément, Duballet Romain, Roux Philippe, Gaudillière-Jami Nadja et al. (2016-03)
    Large-Scale 3D Printing of Ultra-High-Performance Concrete:
    A New Processing Route for Architects and Builders
  9. Guo Xiaolu, Yang Junyi, Xiong Guiyan (2020-09)
    Influence of Supplementary Cementitious Materials on Rheological Properties of 3D Printed Fly-Ash-Based Geopolymer
  10. Kazemian Ali, Yuan Xiao, Cochran Evan, Khoshnevis Behrokh (2017-04)
    Cementitious Materials for Construction-Scale 3D Printing:
    Laboratory Testing of Fresh Printing Mixture
  11. Khalil Noura, Aouad Georges, Cheikh Khadija, Rémond Sébastien (2017-09)
    Use of Calcium-Sulfoaluminate-Cements for Setting-Control of 3D Printing Mortars
  12. Le Thanh, Austin Simon, Lim Sungwoo, Buswell Richard et al. (2012-01)
    Mix-Design and Fresh Properties for High-Performance Printing Concrete
  13. Lee Hojae, Kim Jang-Ho, Moon Jae-Heum, Kim Won-Woo et al. (2019-12)
    Evaluation of the Mechanical Properties of a 3D Printed Mortar
  14. Lee Keon-Woo, Lee Hojae, Choi Myoungsung (2022-07)
    Correlation Between Thixotropic Behavior and Buildability for 3D Concrete Printing
  15. Lim Sungwoo, Buswell Richard, Valentine Philip, Piker Daniel et al. (2016-06)
    Modelling Curved-Layered Printing Paths for Fabricating Large-Scale Construction Components
  16. Liu Huawei, Liu Chao, Bai Guoliang, Wu Yiwen et al. (2022-04)
    Influence of Pore-Defects on the Hardened Properties of 3D Printed Concrete with Coarse Aggregate
  17. Liu Huawei, Liu Chao, Wu Yiwen, Bai Guoliang et al. (2022-09)
    3D Printing Concrete with Recycled Coarse Aggregates:
    The Influence of Pore-Structure on Inter-Layer Adhesion
  18. Lowke Dirk, Dini Enrico, Perrot Arnaud, Weger Daniel et al. (2018-07)
    Particle-Bed 3D Printing in Concrete Construction:
    Possibilities and Challenges
  19. Ma Guowei, Salman Nazar, Wang Li, Wang Fang (2020-02)
    A Novel Additive Mortar Leveraging Internal Curing for Enhancing Inter-Layer Bonding of Cementitious Composite for 3D Printing
  20. Malaeb Zeina, Sakka Fatima, Hamzeh Farook (2019-02)
    3D Concrete Printing:
    Machine Design, Mix Proportioning, and Mix Comparison Between Different Machine Setups
  21. Marchon Delphine, Kawashima Shiho, Bessaies-Bey Hela, Mantellato Sara et al. (2018-05)
    Hydration- and Rheology-Control of Concrete for Digital Fabrication:
    Potential Admixtures and Cement-Chemistry
  22. Moini Mohamadreza, Olek Jan, Zavattieri Pablo, Youngblood Jeffrey (2022-04)
    Early-Age Buildability-Rheological Properties Relationship in Additively Manufactured Cement-Paste Hollow Cylinders
  23. Panda Biranchi, Ruan Shaoqin, Unluer Cise, Tan Ming (2018-11)
    Improving the 3D Printability of High-Volume Fly-Ash Mixtures via the Use of Nano-Attapulgite-Clay
  24. Reiter Lex, Wangler Timothy, Roussel Nicolas, Flatt Robert (2018-06)
    The Role of Early-Age Structural Build-Up in Digital Fabrication with Concrete
  25. Ren Chuangnan, Hua Dongliang, Bai Yonghui, Wu Shuang et al. (2022-06)
    Preparation and 3D Printing Building Application of Sulfoaluminate-Cementitious-Material Using Industrial Solid-Waste
  26. Shahzad Qamar, Wang Xujiang, Wang Wenlong, Wan Yi et al. (2020-06)
    Coordinated Adjustment and Optimization of Setting-Time, Flowability, and Mechanical Strength for Construction 3D Printing Material Derived from Solid Waste
  27. Sun Xiaoyan, Wang Qun, Wang Hailong, Chen Long (2020-03)
    Influence of Multi-Walled Nanotubes on the Fresh and Hardened Properties of a 3D Printing PVA Mortar Ink
  28. Tao Yaxin, Mohan Manu, Rahul Attupurathu, Yuan Yong et al. (2022-08)
    Stiffening Controllable Concrete Modified with Redispersible Polymer Powder for Twin-Pipe Printing
  29. Tay Yi, Qian Ye, Tan Ming (2019-05)
    Printability-Region for 3D Concrete Printing Using Slump- and Slump-Flow-Test
  30. Vallurupalli Kavya, Farzadnia Nima, Khayat Kamal (2021-01)
    Effect of Flow Behavior and Process-Induced Variations on Shape Stability of 3D Printed Elements:
    A Review
  31. Wolfs Robert, Bos Freek, Salet Theo (2019-03)
    Hardened Properties of 3D Printed Concrete:
    The Influence of Process Parameters on Inter-Layer Adhesion
  32. Wu Peng, Wang Jun, Wang Xiangyu (2016-04)
    A Critical Review of the Use of 3D Printing in the Construction Industry
  33. Zhang Yu, Zhang Yunsheng, She Wei, Yang Lin et al. (2019-01)
    Rheological and Hardened Properties of the High-Thixotropy 3D Printing Concrete

2 Citations

  1. Iqbal Imtiaz, Kasim Tala, Besklubova Svetlana, Inqiad Waleed et al. (2025-12)
    Exploring Knowledge Domains and Future Research Directions in 3D Printed Concrete:
    A Bibliometric and Systematic Review
  2. Peng Yiming, Unluer Cise (2024-06)
    Performance and Microstructural Development of 3D Printable MgO-SiO2 Mixes Containing Magnesium-Silicate-Monohydrate

BibTeX
@article{xu_zhan_li_yin.2023.EoAotMPRaPPoPB3,
  author            = "Zhuoyue Xu and Dawang Zhang and Hui Li and Le Yin and Haiping Song and Wanchun Wang and Siyu Zhang",
  title             = "Effects of Additives on the Mechanical Properties, Rheology, and Printing Properties of PCC-Based 3DPMs",
  doi               = "10.1016/j.ceramint.2023.06.090",
  year              = "2023",
  journal           = "Ceramics International",
}
Formatted Citation

Z. Xu, “Effects of Additives on the Mechanical Properties, Rheology, and Printing Properties of PCC-Based 3DPMs”, Ceramics International, 2023, doi: 10.1016/j.ceramint.2023.06.090.

Xu, Zhuoyue, Dawang Zhang, Hui Li, Le Yin, Haiping Song, Wanchun Wang, and Siyu Zhang. “Effects of Additives on the Mechanical Properties, Rheology, and Printing Properties of PCC-Based 3DPMs”. Ceramics International, 2023. https://doi.org/10.1016/j.ceramint.2023.06.090.